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There is some disagreement on which configuration has the lowest energy. Chemistry textbooks quote the electron configuration of nickel as [Ar] 4s2 3d8, which can also be written [Ar] 3d8 4s2. In organometallic chemistry, metal carbonyls serve as precursors for the preparation of other organometalic complexes. The terminology is typically applied to coordination and organometallic complexes, but resembles the Sn2 mechanism in organic chemistry. The MO diagram correlates with the experimental photoelectron spectrum for nitrogen. The 1σ electrons can be matched to a peak at 410 eV (broad), the 2σg electrons at 37 eV (broad), the 2σu electrons at 19 eV (doublet), the 1πu4 electrons… Also known as the Pearson acid-base concept, HSAB is widely used in chemistry for explaining stability of compounds, reaction mechanisms and pathways.